Search results for "Shell (structure)"

showing 4 items of 4 documents

Analysis of the Electronic Structure of Non-Spherical Ligand-Protected Metal Nanoclusters: The Case of a Box-Like Ag67

2016

In this work we introduce a new strategy to investigate the electronic shell structure of ligand-protected metal nanoclusters of polyhedral core shape. The central idea is to identify the symmetry of the Kohn–Sham molecular orbitals of an atomistic structure based on their projection onto the electronic states of a jellium system with a similar shape of the background charge density. Herein, we study the connection between a reduced atomistic model of the recently reported box-like [Ag67(SR)32(PR3)8]3+ nanocluster and a jellium box consisting of 32 free electrons. With this approach, we determine the symmetry of electronic states of the metal core and identify those that are involved in the…

Free electron modelJelliumnanoclusters02 engineering and technologyElectronic structureligand-protected metal nanoclusters010402 general chemistry01 natural sciencesMolecular physicsProjection (linear algebra)NanoclustersPhysics::Atomic and Molecular ClustersMolecular orbitalPhysical and Theoretical Chemistryta116Physicsta114electronic shell structures021001 nanoscience & nanotechnologySymmetry (physics)0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsGeneral EnergyAtomic electron transitionAtomic physics0210 nano-technologyThe Journal of Physical Chemistry C
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Shell structure beyond the proton drip line studied via proton emission from deformed 141Ho

2008

Abstract Fine structure in proton emission from the 7 / 2 − [ 523 ] ground state and from the 1 / 2 + [ 411 ] isomer in deformed nucleus 141Ho was studied by means of fusion-evaporation reactions and digital signal processing. Proton transitions to the first excited 2+ state in 140Dy, with the branching ratio of I p g s ( 2 + ) = 0.9 ± 0.2 % and I p m ( 2 + ) = 1.7 ± 0.5 % , were observed. The data are analyzed within the non-adiabatic weak coupling model assuming a large quadrupole deformation of the daughter nucleus 140Dy as predicted by the self-consistent theory. Implications of this result on coexistence effects around N = 74 are discussed. Significant modifications of the proton shell…

PhysicsNuclear and High Energy PhysicsProtonProton radioactivity; Proton shell structure; Two-body tensor interactionsNuclear TheoryHadronElementary particleExcited stateQuadrupoleProton emissionAtomic physicsNuclear ExperimentNucleonGround statePhysics Letters B
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Analysis of the Electronic Structure of Non-Spherical Ligand-Protected Metal Nanoclusters : The Case of a Box-Like Ag67

2017

In this work we introduce a new strategy to investigate the electronic shell structure of ligand-protected metal nanoclusters of polyhedral core shape. The central idea is to identify the symmetry of the Kohn–Sham molecular orbitals of an atomistic structure based on their projection onto the electronic states of a jellium system with a similar shape of the background charge density. Herein, we study the connection between a reduced atomistic model of the recently reported box-like [Ag67(SR)32(PR3)8]3+ nanocluster and a jellium box consisting of 32 free electrons. With this approach, we determine the symmetry of electronic states of the metal core and identify those that are involved in the…

Physics::Atomic and Molecular Clustersnanoclusterselectronic shell structuresligand-protected metal nanoclusters
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Studying Gamow-Teller transitions and the assignment of isomeric and ground states at $N=50$

2022

Direct mass measurements of neutron-deficient nuclides around the N=50 shell closure below $^{100}$Sn were performed at the FRS Ion Catcher (FRS-IC) at GSI, Germany. The nuclei were produced by projectile fragmentation of $^{124}$Xe, separated in the fragment separator FRS and delivered to the FRS-IC. The masses of 14 ground states and two isomers were measured with relative mass uncertainties down to 1×10−7 using the multiple-reflection time-of-flight mass spectrometer of the FRS-IC, including the first direct mass measurements of $^{98}$Cd and $^{97}$Rh. A new QEC=5437±67 keV was obtained for $^{98}$Cd, resulting in a summed Gamow-Teller (GT) strength for the five observed transitions (0+…

nuclear isomersNuclear and High Energy PhysicsMultiple-reflection time-of-flight massNuclear shell structuremultiple-reflection time-of-flight mass[PHYS.NEXP] Physics [physics]/Nuclear Experiment [nucl-ex]N = 50 isotonesFOS: Physical sciencesGamow-Teller transition?s strength114 Physical sciencesSpectrometerexotic nucleiGamow-Teller transition's strengthnuclear shell structureNuclear isomersspectrometerN=50 isotonesNuclear Experiment (nucl-ex)ydinfysiikkaNuclear ExperimentExotic nuclei
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